غشاهای کامپوزیتی مبتنی بر گرافن برای نانوصافش: عملکرد و چشم‌اندازهای آینده
محورهای موضوعی : پليمرها و نانوفناوری
1 - دانشگاه بیرجند
کلید واژه: غشا, نانوصافش, تصفیه, گرافن,
چکیده مقاله :
نانو صافش (Nanofiltration) یکی از پرکاربردترین فرایندهای غشایی برای تصفیه آب بوده که ارزش عملی بالایی دارد؛ زیرا تعداد زیادی گونه‌های شیمیایی از طریق این فرایند جدا می‌شوند. معمولاً برای نانوصافش، عملیات پرمصرف انرژی شامل ایجاد فشار کافی برای دفع پرش ها و مواد شیمیایی با وزن مولکولی پایین در سطح غشا، درگیر هستند. تحولات اخیر در سنتز غشاهای نانوکامپوزیت با گرافن و مشتقات گرافن منجر به افزایش نیاز انرژی و افزایش عملکرد غشاها شده است. در تحقیق حاضر، پیشرفت‌های اخیر در زمینه غشاهای کامپوزیتی مبتنی بر گرافن برای نانوصافش با کاربردهایی برای هر دو نوع حلال مبتنی بر محلول‌های آبی و حلال‌های آلی ارائه شده است. این تحقیق به‌ویژه بر عملکرد غشاها و کاربردهای این مواد برای دفع نمک ها (Na+، Mg2+)، فلزات سنگین (Li2+) و ترکیبات آلی با وزن مولکولی پایین (رنگ های متیلن آبی، قرمز کنگو، مستقیم قرمز، متیل، نارنجی، سبز واکنشی 13 و غیره) متمرکز خواهد بود. روش های سنتز مدرن مانند پلیمرشدن سطحی (Interfacial Polymerization) برای به‌دست آوردن غشاهای نانوصافش کامپوزیتی لایه نازک نیز ارائه شده است.
چکیده انگلیسی:
Nanofiltration is one of the most widely used membrane processes for water purification with high practical value because of a large number of chemical species that are separated through this process. Usually, for nanofiltration, high energy–con- suming operations are involved including the generation of enough pressure for the rejection of jumps and lower molecular weight chemicals at the surface of the membrane. Recent developments in the synthesis of nanocomposite membranes with graphene and graphene derivatives have led to an increase in energy requirements and the increase in membranes perfor- mances. In the present review, we have presented the recent advances in the field of graphene-based composite membranes for nanofiltration with applications for both types of based solvents—aqueous solutions and organic solvents. The presentation will be focused especially on the performances of membranes and applications of these materials for the rejection of salts (Na+, Mg2+), heavy metals (Li2+), and lower molecular weight organic compounds (methylene blue, Congo red, Direct Red, Methyl orange, Reactive green 13, etc.). Modern synthesis methods like interfacial polymerization for obtaining thin-film composite nanofiltration membranes are also presented. Nanofiltration is one of the most widely used membrane processes for water purification with high practical value because of a large number of chemical species that are separated through this process.
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1. Ulbricht M., Advanced Functional Polymer Membranes, Polymer, 47, 2217–2262, 2006.
2. Lehn J.M., Supramolecular Chemistry: Concepts and Perspectives. Wiley ISBN 3–527- 2931, 1–6, 1995.
3. Kang X., Cheng Y., Wen Y., Qi J., Li X., Bioinspired Codeposited Preparation of GO Composite Loose Nanofiltration Membrane for Dye Contaminated Wastewater Sustainable Treatment, Journal of Hazardous Materials, 400, 123121, 2020.
4. Palla-Papavlu A., Voicu S.I., Dinescu M., Sensitive Materials and Coating Technologies for Surface Acoustic Wave Sensors, Chemosensors, 9, 105, 2021.
5. Chiulan I., Heggset E.B., Voicu S.I., Chinga-Carrasco G., Photopolymerization of Biobased Polymers in A Biomedical Engineer- Ing Perspective, Biomacromolecules, 225, 1795–1814, 2021. 6. Muhulet A., Tuncel C., Miculescu F., Pandele A.M., Bobirica C., Orbeci C., Bobirica L., Palla-Papavlu A., Voicu S.I., Synthesis and Characterization of Polysulfone-Tio2 Doped MWCNT Composite Membranes by Sonochemical Method, Applied Physics A, 126, 233, 2020.
7. Pandele A.M., Constantinescu A., Radu I.C., Miculescu F., Voicu S.I., Ciocan L.T., Synthesis and Characterization Of PLA– Microstructured Hydroxyapatite Composite Films, Materials, 13, 274, 2020.
8. Oprea M., Voicu S.I., Recent Advances in Composites Based On Cellulose Derivatives for Biomedical Applications, Carbohydrate Polymers, 247, 116683, 2020.
9. Oprea M., Voicu S.I., Cellulose Composites with Graphene for Tissue Engineering Applications. Materials, 1323, 5347, 2020.
10. Oprea M., Voicu S.I., Recent Advances in Applications of Cellulose Derivatives-Based Composite Membranes with Hydroxyapatite, Materials, 13, 2481, 2020.
11. Pandele A.M., Iovu H., Orbeci C., Tuncel C., Nicolescu A., Deleanu C., Miculescu F., Voicu S.I., Surface Modified Cellulose Acetate Membranes for the Reactive Retention of Tetracycline, Separation and Purification Technology, 249, 117145, 2020.
12. Raicopol M.D., Andronescu C., Voicu S.I., Vasile E., Pandele A.M., Cellulose Acetate/Layered Double Hydroxide Adsorptive Membranes for Efficient Removal of Pharmaceutical Environmental Contaminants, Carbohydrate Polymers, 214, 204–212, 2019.
13. Voicu S.I., Thakur V.K., Aminopropyltriethoxysilane as A Linker for Cellulose-Based Functional Materials: New Horizons and Future Challenges, Current Opinion in Green and Sustainable Chemistry, 30, 100480, 2021.
14. Ionita M., Crica L.E., Voicu S.I., Pandele A.M., Iovu H., Fabrication of Cellulose Triacetate/Graphene Oxide Porous Membrane, Polymers for Advanced Technologies, 27, 350–357, 2016.
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