Graphene‑based composite membranes for nanofiltration: performances and future perspectives
Subject Areas :
1 - University of Birjand
Keywords: Membrane, Nanofiltration, Graphene,
Abstract :
Nanofiltration is one of the most widely used membrane processes for water purification with high practical value because of a large number of chemical species that are separated through this process. Usually, for nanofiltration, high energy–con- suming operations are involved including the generation of enough pressure for the rejection of jumps and lower molecular weight chemicals at the surface of the membrane. Recent developments in the synthesis of nanocomposite membranes with graphene and graphene derivatives have led to an increase in energy requirements and the increase in membranes perfor- mances. In the present review, we have presented the recent advances in the field of graphene-based composite membranes for nanofiltration with applications for both types of based solvents—aqueous solutions and organic solvents. The presentation will be focused especially on the performances of membranes and applications of these materials for the rejection of salts (Na+, Mg2+), heavy metals (Li2+), and lower molecular weight organic compounds (methylene blue, Congo red, Direct Red, Methyl orange, Reactive green 13, etc.). Modern synthesis methods like interfacial polymerization for obtaining thin-film composite nanofiltration membranes are also presented. Nanofiltration is one of the most widely used membrane processes for water purification with high practical value because of a large number of chemical species that are separated through this process.
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1. Ulbricht M., Advanced Functional Polymer Membranes, Polymer, 47, 2217–2262, 2006.
2. Lehn J.M., Supramolecular Chemistry: Concepts and Perspectives. Wiley ISBN 3–527- 2931, 1–6, 1995.
3. Kang X., Cheng Y., Wen Y., Qi J., Li X., Bioinspired Codeposited Preparation of GO Composite Loose Nanofiltration Membrane for Dye Contaminated Wastewater Sustainable Treatment, Journal of Hazardous Materials, 400, 123121, 2020.
4. Palla-Papavlu A., Voicu S.I., Dinescu M., Sensitive Materials and Coating Technologies for Surface Acoustic Wave Sensors, Chemosensors, 9, 105, 2021.
5. Chiulan I., Heggset E.B., Voicu S.I., Chinga-Carrasco G., Photopolymerization of Biobased Polymers in A Biomedical Engineer- Ing Perspective, Biomacromolecules, 225, 1795–1814, 2021. 6. Muhulet A., Tuncel C., Miculescu F., Pandele A.M., Bobirica C., Orbeci C., Bobirica L., Palla-Papavlu A., Voicu S.I., Synthesis and Characterization of Polysulfone-Tio2 Doped MWCNT Composite Membranes by Sonochemical Method, Applied Physics A, 126, 233, 2020.
7. Pandele A.M., Constantinescu A., Radu I.C., Miculescu F., Voicu S.I., Ciocan L.T., Synthesis and Characterization Of PLA– Microstructured Hydroxyapatite Composite Films, Materials, 13, 274, 2020.
8. Oprea M., Voicu S.I., Recent Advances in Composites Based On Cellulose Derivatives for Biomedical Applications, Carbohydrate Polymers, 247, 116683, 2020.
9. Oprea M., Voicu S.I., Cellulose Composites with Graphene for Tissue Engineering Applications. Materials, 1323, 5347, 2020.
10. Oprea M., Voicu S.I., Recent Advances in Applications of Cellulose Derivatives-Based Composite Membranes with Hydroxyapatite, Materials, 13, 2481, 2020.
11. Pandele A.M., Iovu H., Orbeci C., Tuncel C., Nicolescu A., Deleanu C., Miculescu F., Voicu S.I., Surface Modified Cellulose Acetate Membranes for the Reactive Retention of Tetracycline, Separation and Purification Technology, 249, 117145, 2020.
12. Raicopol M.D., Andronescu C., Voicu S.I., Vasile E., Pandele A.M., Cellulose Acetate/Layered Double Hydroxide Adsorptive Membranes for Efficient Removal of Pharmaceutical Environmental Contaminants, Carbohydrate Polymers, 214, 204–212, 2019.
13. Voicu S.I., Thakur V.K., Aminopropyltriethoxysilane as A Linker for Cellulose-Based Functional Materials: New Horizons and Future Challenges, Current Opinion in Green and Sustainable Chemistry, 30, 100480, 2021.
14. Ionita M., Crica L.E., Voicu S.I., Pandele A.M., Iovu H., Fabrication of Cellulose Triacetate/Graphene Oxide Porous Membrane, Polymers for Advanced Technologies, 27, 350–357, 2016.
15. Voicu S.I., Pandele A.M., Vasile E., Rughinis R., Crica L.E., Pilan L., Ionita M., The Impact of Sonication Time Through Poly-Sulfonegraphene Oxide Composite Films Properties, Digest Journal of Nanomaterials and Biostructures, 8, 1389–1394, 2013.
16. Pandele A.M., Serbanescu O.S., Voicu S.I., Polysulfone Composite Membranes with Carbonaceous Structure, Synthesis and applications coatings, 107, 609, 2020.
17. Satulu V., Mitu B., Pandele A.M., Voicu S.I., Kravets L., Dinescu G., Composite Polyethylene Terephthalate Track Membranes with Thin Teflon-like Layers: Preparation and Surface Properties, Applied Surface Science, 476, 452–459, 2019.
18. Serbanescu O.S., Voicu S.I., Thakur V.K., Polysulfone Functionalized Membranes: Properties and Challenges, Materials Today Chemistry, 17, 100302, 2020.
19. Serbanescu O.S., Pandele A.M., Miculescu F., Voicu S.I., Synthesis and Characterization of Cellulose Acetate Membranes with Self-Indicating Properties by Changing the Membrane Surface Color for Separation of Gd (III), Coatings, 10, 468, 2020.
20. Voicu S.I., Dobrica A., Sava S., Ivan A., Naftanaila L., Cationic Surfactants-Controlled Geometry and Dimensions of Polymeric Membrane Pores, The Journal of Optoelectronics and Advanced Materials, 14, 923–928, 2012.
21. Zhou M., Chen J., Zhou W., Sun J., Tang H., Developing Composite Nanofiltration Membranes with Highly Stable Antifouling Property Based on Hydrophilic Roughness, Separation and Purification Technology, 256, 117799, 2021.
22. Zhang Y., Chung T.-S., Graphene Oxide Membranes for Nanofiltration, Current Opinion in Chemical Engineering, 16, 9–15, 2017.
23. Kang X., Liu X., Liu J., Wen Y., Qi J., Li X., Spin Assisted Interfacial Polymerization Strategy for Graphene Oxide-Polyamide Composite Nanofiltration Membrane with High Performance, Applied Surface Science, 508, 145198, 2020.
24. Hu R.R., He Y.J., Huang M.R., Zhao G.K., Zhu H.W., Strong Adhesion of Graphene Oxide Coating on Polymer Separation Membranes, Langmuir, 34, 10569–10579, 2018.
25. Xie Q.L., Zhang S.S., Hong Z., Ma H.J., Zeng B.R., Gong X., Shao W.Y., Wang Q.Q., A Novel Double-Modified Strategy to Enhance the Performance of Thin-Film Nanocomposite Nanofiltration Membranes: Incorporating Functionalized Graphene into Supporting and Selective Layers, Chemical Engineering Journal, 368, 186–201, 2019.
26. Zheng S.X., Tu Q.S., Urban J.J., Li S.F., Mi B.X., Swelling of Graphene Oxide Membranes in Aqueous Solution: Characterization of Interlayer Spacing and Insight into Water Transport Mechanisms, ACS Nano, 11, 6440–6450, 2017.
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