Polyoxymetal / polymer composites An overview of synthesis methods and their properties
Subject Areas :
Marziyeh
Kavian
1
Milad
Ghani
2
Jahan Bakhsh
Raoof
3
Keywords: Multiplayer, Host polymeric materials, POM, Molecular cloud modification, Surfactant-encapsulated POM,
Abstract :
This article gives an overview of the manufacturing method and properties of composites containing polyoxymetals / polymers. Polyoxometals (POMs) are discrete, molecular, metal oxide clusters of various sizes ranging from one to several nanometers that exhibit different topologies and diverse chemical and electronic properties. POMs show very strong acidity, which makes them effective acid catalysts for specific reactions such as esterification, hydrolysis, Friedel-Craft alkylation, and tetrahydrofuran ring-opening polymerization. The integration of mineral components with polymer matrices will combine the properties of the mineral phase with polymers and create new functions. Mineral micrometer building blocks have been used to enhance mechanical strength, improve thermal and chemical stability, and improve the performance of polymeric materials. With the rapid development of nanotechnology, polymers can also be used as a substrate for the stabilization of nanostructures, which will eventually have the properties of nanostructures and polymer substrates at the same time. Methods such as physical composition, electrostatic adsorption, covalent bonding, and supermolecular modification are the main methods for combining POM in organic or inorganic polymer matrices (eg silica). Polyoxymetal / polymer composites have various properties such as unique optical, electrical or catalytic properties of polyoxymetals and the optimal processing and stability of polymer matrices. POM/ polymer composites may have many applications in optics, electronics, biology, medicine and catalysis
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