Porous polymers and recent developments in organic covalent frameworks applications in magnetic solid phase extraction method for use in food analysis
Subject Areas :
Parastoo
Fooladi
1
(Faculty of chemistry.)
Milad
Ghani
2
(شیمی)
Keywords: Magnetic covalent organic frameworks, solid phase magnetic extraction, extraction mechanism of food contaminants, food safety,
Abstract :
Magnetic Covalent Organic Frameworks are one of the adsorbents used in Magnetic Solid-Phase Extraction, which are due to easy synthesis, compatibility with the environment, high porosity, easy changes of functional groups and structures. pre-engineered, have been widely used in food extraction and analysis. In this paper, the polymer-based MSPE method of MCOF will be described. Also, the latest design and fabrication methods of various MCOFs will be briefly explained. is given. The development and application of MCOFs combined with MSPE technology shows great potential in food safety monitoring. MCOFs are due to their unique structural and chemical properties such as strong magnetic properties, high specific surface area, functional groups, permanent porosity and Excellent chemical stability, excellent magnetic adsorbent are considered. Functional groups of MCOFs with monomers or polymers that contain different functional groups are a scientific approach to develop new MCOFs that can effectively adsorb contaminants in food. Effectively texture effect. removes, and improves extraction efficiency. This review describes the recent progress in the application of MCOFs in the preconcentration and analysis of pesticides, pharmaceuticals, polymer additives, pyrolysis products and other types of food contaminants. Finally, it examines future challenges and possible solutions in the analysis of the food samples.
[1] Qin P., Chen D., Li D., Li M., Mu M., Gao Y., Zhu S., Lu M., Synthesis of spindle-like amino-modified Zn/Fe bimetallic metal-organic frameworks as sorbents for dispersive solid-phase extraction and preconcentration of phytohormoes in vegetable
samples, Food Chemistry, 409, 13527, 2023. [2] Liang, J.; Huang, Y.-B.; Cao, R., Metal–Organic Frameworks and Porous Organic Polymers for Sustainable Fixation of Carbon Dioxide into Cyclic Carbonates. Coord. Chem. Rev. 2019
. [3] Zhou, M.; Wang, T.; He, Z.; Xu, Y.; Yu, W.; Shi, B.; Huang, K., Synthesis of Yolk–Shell Magnetic Porous Organic Nanospheres
for Efficient Removal of Methylene Blue from Water. ACS Sustain. Chem. Eng. 2019. [4] Ryu, S. H.; Lee, D. H.; Lee, S. M.; Kim, H. J.; Ko, Y.-J.; Ko, K. C.; Son, S. U., Morphology Engineering of a Suzuki Coupling-Based Microporous Organic Polymer (MOP) Using a Sonogashira Coupling-Based MOP for Enhanced Nitrophenol Sensing in
Water. Chem. Commun. 2019. [5] Castaldo, R.; Avolio, R.; Cocca, M.; Gentile, G.; Errico, M. E.; Avella, M.;Carfagna, C.; Ambrogi, V., A Versatile Synthetic
Approach toward Hyper-Cross- Linked Styrene-Based Polymers and Nanocomposites. Macromolecules 2017. [6] Biswal B. P., et al., "Chemically Stable Covalent Organic Framework (COF)- Polybenzimidazole Hybrid Membranes:
Enhanced Gas Separation through Pore Modulation", Chem. A Eur. J., 2016, vol. 22, pp. 4695–4699. [7] Reddy, S. S.; Kalla, R. M. N.; Varyambath, A.; Kim, I., Sulfonic acid Functionalized Hyper-Cross-Linked Polymer: An Efficient
Heterogeneous Acid Catalyst for the Synthesis of N-Containing Bisphosphonates. Catal. Commun.2019. [8] James, A. M.; Harding, S.; Robshaw, T.; Bramall, N.; Ogden, M. D.; Dawson,R., Selective Environmental Remediation of
Strontium and Cesium Using Sulfonated Hyper-Cross-Linked Polymers (SHCPs). ACS Appl. Mater. Interfaces 2019. [9] Gao, H.; Ding, L.; Bai, H.; Li, L., Microporous Organic Polymers Based on Hyper-Crosslinked Coal Tar: Preparation and
Application for Gas Adsorption. ChemSusChem 2017. [10] F. J. Uribe-Romo, J. R. Hunt, H. Furukawa, C. Klöck, M. O’Keeffe, and O. M. Yaghi,"A Crystalline Imine-Linked 3-D Porous
Covalent Organic Framework," Journal of the American Chemical Society, vol. 131, no. 13, pp. 4570-4571, 2009. [11] P. Kuhn, M. Antonietti, and A. Thomas, "Porous, Covalent Triazine-Based Frameworks Prepared by Ionothermal
Synthesis," Angewandte Chemie International Edition, vol. 47, no. 18, pp. 3450-3453, 2008. [12] K. Wang, L.-M. Yang, X. Wang, L. Guo, G. Cheng, C. Zhang, S. Jin, B. Tan, and A. Cooper, "Covalent Triazine Frameworks via a Low-Temperature Polycondensation Approach," Angewandte Chemie International Edition, vol. 56, no. 45, pp. 14149-14153,
2017. [13] P .Bhanja, K. Bhunia, S. K. Das, D. Pradhan, R. Kimura, Y. Hijikata, S. Irle, and A.Bhaumik, "A New Triazine-Based Covalent
Organic Framework for High-Performance Capacitive Energy Storage," ChemSusChem, vol. 10, no. 5, pp. 921-929, 2017. [14] M. Dinari, M. M. Momeni, and M. Afshari, "Fabrication and characterization of hybrid films based on polyaniline and
graphitic carbon nitride nanosheet," Journal of Applied Polymer Science, vol. 133, no. 40, 2016. [15] Yan Z., He M., Chen B., Hu B., Covalent triazine frameworks/cobalt composites for magnetic solid phase extraction of pyrethroids from food samples followed by gas chromatography-flame ionization detection, Advances in Sample Preparation,
1, 100006, 2022. [16] Liu G., Chen H., Zhang W., Ding Q., Wang J., Zhang L., Facile mechano-chemistry synthesis of magnetic covalent organic framework composites for efficient extraction of microcystins in lake water samples, Analytica Chimica Acta, 1166, 338539,
2021. [17] Liu X., Li S., Wang D., Ma Y., Liu X., Ning M., Theoretical study on the structure and cationeanion interaction of
triethylammonium chloroaluminate ionic liquid, Computational and Theoretical Chemistry, 1073, 67e74, 2015. [18] Pandiselvam R., Kaavya R., Jayanath Y., Veenuttranon K., Lueprasitsakul P., Divya V., Kothakota A., Ramesh S.V., Ozone as a novel emerging technology for the dissipation of pesticide residues in foodsea review, Trends in Food Science and
Technology, 97, 38e54, 2020.