MOFCOF composites a review of synthesis methods and applications
Subject Areas :
Milad
Ghani
1
Marziyeh
Kavian
2
Keywords: MOF, COF, MOF@COF composites, Applications,
Abstract :
In the past decades, porous materials have attracted a lot of attention in physics, chemistry and materials science. Among various compounds, metal-organic frameworks (Metal organic frameworks, MOFs) and covalent organic frameworks (COFs), as crystalline porous materials, were developed at a very high speed. MOFs are a subgroup of porous compounds in which organic ligands are connected together with metal cations. COFs are two- or three-dimensional organic solids with extended structures in which the building blocks are connected by strong covalent bonds. These compounds have unique advantages including well-defined and tunable structures, large surface area, high porosity, and ease of framework modification, which make them ideal host substrates for various guests including polymers, metal oxide nanoparticles, and semiconductors to create Converts MOF or COF-based multistructures. Compared to single-component compounds, polycomposites always show new properties due to their synergistic effects. Therefore, to further improve their performance and expand their applications, many efforts have been made to design and fabricate various MOF or COF-based multi-structures. Therefore, in this study, the integration of MOFs and COFs, their manufacturing methods, and the applications of these multiple structures will be investigated. Moreover, the capability of the prepared sorbents in various fields such as sorbent, catalysis and other format will be discussed. Metal–organic frameworks (MOFs) are a class of compounds consisting of metal clusters (also known as SBUs) coordinated to organic ligands to form one-, two-, or three-dimensional structures.
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